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陈谦
发布人:李思曼  发布时间:2016-02-29   浏览次数:10

基本信息

哈工大基础与交叉科学研究院

哈尔滨工业大学科学园2A 1319室

哈尔滨市南岗区一匡街2号 3026信箱

电子邮件:chenqian@hit.edu.cn


教育经历

1993.9—1997.7 云南师范大学 化学系,本科,理学学士学位;

1997.9—2000.7 兰州大学化学系,有机化学硕士;

2002.10—2006.3 日本京都大学,药学博士学位;

2007.3—2008.4 日本理化学研究所,博士后


工作经历

2008.08--至今  哈尔滨工业大学 有机化学学科 副教授


研究方向

l   金属有机化学:主要包括碳-碳键及碳-杂原子键的构筑、CO2,CO,O2等小分子的活化与利用、水的氧化与分解制氢等。

l   不对称合成:以设计、合成新型配体及催化剂为起点,探索新型催化反应为主要研究内容,以合成制备新型或有用的化合物为目标。主要包括:手性配体的设计、合成及其应用;天然产物的不对称全合成。  

l   环境(水)中有机污染物的选择性氧化与降解:设计与合成具有新颖结构的配体,并深入研究其在铁、锰、钴催化的环境有机污染物的选择性氧化或深度氧化性降解的行为,探明理解催化氧化的机理。  

l   重金属的选择性识别与去除:设计、合成具有优良配位螯合性能的分子,并深入研究其对Hg2+、Cd2+、Cu2+、Cr3+等重金属离子的选择性吸附行为,探明吸附与解离的机理,并将吸附性能优良的分子制备成可重复利用的吸附材料。  


发表论文

1. Gao, G.L.; Chen, Q. Recent Advance in Utilities of Active Iodine Reagents  as Organo-Catalyts in Organic Synthesis. Current Organocatalysis, 2015, 2,  accepted.

2. Chen, Q.; Liu, C.; Guo, F.; Li, L. A Palladium-catalyzed Arylation of  N-Acyl-N,O-Acetals with Arylboronic Reagents: Synthesis of Diarylmethylamines  Protected by Easily Removable Acyl Group. Tetrahedron 2015, 71, 5337.

3. Chen, Q.; Li, L.; Guo, F.; Mao, Z The first application of C2-symmetric  chiral sulfurous diamide as efficient sulfureolefin hybrid ligands for  Rh-catalyzed asymmetric 1,4-addition reactions. Tetrahedron 2015, 71,  http://dx.doi.org/10.1016/j.tet.2015.01.054.

4. Wang, Z.; Chen, Z.; Chang, J.; Shen, J.; Kang, J.; Yang, L.; Chen, Q. A  novel cementitious microfiltration membrane: mechanisms of pore  formation and properties for water permeation. RSC Adv., 2015, 5, 99–108

5. Chang, J.; Chen, Z.; Wang , Z.; Shen, J.; Chen, Q.; Kang, J.; Yang, L.;  Liu, X.; Nie, X. Ozonation degradation of microcystin-LR in aqueous solution:  Intermediates, byproducts and pathways. Water Research 2014, 63, 52-61.

6. Chen, Q.; Chen, C.; Guo F.; Xia, W. Application of chiral  N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl  boronic acids with cyclic enones. Chem.Commun., 2013, 49, 6433.

7. Chen, Q. Recent Advances of Immobilized Catalysts for Enantioselective  Processes. Current Organic Chemistry, 2013, 17, 1303-1324.

8. Han, Y.; Chen, Z.; Tong, L.; Yang, L.; Shen,J.; Wang, B; Liu, Y.; Chen, Q.  Reduction of N-Nitrosodimethylamine with zero-valent zinc. Water Research 2013,  47, 216-224.

9. Chen, H.; Chen, Q. Synthesis of Chirl N,P-ligands Derived from L-Proline  and   Its Application to 1,3-Dipolar Cycloaddition. Chin. J. Org. Chem. 2013,  33, 848-853.

10. Hao, X.; Chen, Q.; Kuriyama, M.; Yamada, K.; Yamamoto, Y.; Tomioka, K.  Rhodium-Catalyzed Asymmetric Phenylation of N-Phosphinoylarylimines with  Triphenylborane. Catal. Sci. Tech., 2011, 1, 62-64.

11. Hao, X.; Chen, Q.; Yamada, K.; Yamamoto, Y.; Tomioka, K. Steric Influence  of N-Phosphorus-arylimines on the Rhodium-Catalyzed Asymmetric Arylation.  Tetrahedron 2011, 67, 6469-6473.

12. Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Wang, X.; Xu, J.; Xia, W.; Yang,  C. pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(V)  phosphate  Cryst.Eng.Comm, 2010, 12, 595–603.

13. Yi, Z.; Yu,X.; Xia, W.; Zhao, L.; Yang, C.; Chen, Q.; Wang, X.; Xu, X.;  Zhang, X. Influence of the steric hindrance of organic amines  on the superamolecular network based on polyoxovanadates. Cryst.Eng.Comm., 2010,  12, 242–249.

14. Hao, X.; Kuriyama, M.; Chen, Q.; Yamamoto, Y.; Yamada, K.; Tomioka, K.  Steric Tuning of the Amidomonophosphane-Rhodium(I) Catalyst in Asymmetric  Addition of Arylboroxines to N-Phosphinoyl Aldimines. Org. Lett. 2009, 11,  4470-4473.

15. Zhao, G.; Yang, C.; Chen, Q.; Jin, J.; Zhang, X.; Zhao, L.; Xia, W.  Photochemical studies on exo-bicyclo[2.1.1]hexyl and bicyclo[3.1.0]hexylaryl  ketones: two approaches for synthesis of enantiomerically enrichedcyclopentene  derivatives. Tetrahedron 2009, 65, 9952.

16. Chen, Q.; Kuriyama, M.; Hao, X.; Soeta, T.; Yamamoto, Y.; Yamada, K.;  Tomioka, K. Chiral Amidophosphane-Rhodium(I)-Catalyzed Asymmetric Conjugate  Arylation of Acyclic Enones with Arylboronic Acids. Chem. Pharm. Bull., 2009,  57, 1024-1027.

17. Yang, C.; Xia, W.-J.; Chen, Q.; Zhang, X.; Li, B.; Gou, B.-Q.  Photochemical Studies on Benzonorbornene Derivatives: Medium Effects and  Asymmetric Induction. Lett. Org. Chem. 2009, 6, 41-43.

18. Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Gu, X.; Xu, J.; Wang, X.; Yang,  C.; Xu, X.; Xia, W. Steric hindrance-dependent rational design and synthesis of  three new Keggin-based supramolecular networks. Dalton Trans., 2009, 9198–9206.  

19. Chen, Q.; Soeta, T.; Kuriyama, M.; Yamada, K.; Tomioka, K. Efficient  Catalytic Asymmetric Synthesis of trans-2-substituted 5-Arylcyclohexanones by  Rhodium-Catalyzed Conjugate Arylation of Racemic 6-Substituted Cyclohexenones.  Adv. Synth. Catal. 2006, 348, 2604-2608.

20. Chen, Q.; Kuriyama, M.; Soeta, T.; Hao, X.; Yamada, K.; Tomioka, K.  Asymmetric Synthesis of 5-Arylcyclohexenones by Rhodium(I)-Catalyzed Conjugate  Arylation of Racemic 5-(Trimethylsilyl)cyclohexenone with Arylboronic Acids.  Org. Lett. 2005, 7, 4439-4441.

21. Kuriyama, M.; Soeta, T.; Hao, X.; Chen, Q.; Tomioka, K.  N-Boc-L-Valine-Connected Amidomonophosphane-Rhodium(I) Catalyst for Asymmetric  Arylation of N-Tosylarylimines with Arylboroxines. J. Am. Chem. Soc. 2004, 126,  8128-8129.

22. Lin, X.;Cai, Y. J.; Li, Z.; Chen, Q.; Liu, Z.L.; Wang, R. Structure  determination, apoptosis induction, and telomerase inhibition of CFP-2, a novel  lichenin from Cladonia furcata. Biochimica et Biophysica Acta  2003,1622,  99-108.

23. Chen, Q.; Chen, X.; Cai, Y.; Wang, F.; Li, Z. X. Isolation, Purification,  and Analysis of Polysaccharides from Adenophora potaninii Kosrh. ZhongYaoCai,  2002, 25, 25-26.

24. Chen, Q.; Lin, X.; Cai, Y.; Li, Z.. Structural analysis of polysaccharide  from Cladonia furcata and its activities. Chem. Res. Chin. Univ. 2001, 17,  226–227.

25. Chen, X.; Wang, F.; Chen, Q.; Qin, X. C.; Li, Z. X. Analysis of  Neurotoxin 3-N-Oxalyl-l-2,3-diaminopropionic Acid and Its α-Isomer in Lathyrus  sativus by High-Performance Liquid Chromatography with  6-Aminoquinolyl-N-hydroxysuccinimidyl Carbamate (AQC) Derivatization. J. Agric.  Food Chem. 2000, 48, 3383-3386.

26. Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. Determination of  neurotoxin 3-N-oxalyl-2,3-diaminopropionic acid and non-protein amino acids in  Lathyrus sativus by precolumn derivatization with 1-fluoro-2,4-dinitrobenzene.  J. Chromatogr. A, 2000, 883, 113-118.

27.  Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. HPLC Determination  of Neurotoxin β-N-oxalyl-L-α,β -diaminopropionic acid and Its α -Isomer in  Lathyrus sativus by Precolumn Derivatization with 1-Fluoro-2,4-dinitrobenzene.  Chin. Chem. Lett. 2000, 11, 435.

28. Wang, F.; Chen, X.; Chen, Q.; Qin, X.C.; Li, Z.X. Determination of  Neurotoxin b-ODAP and Non-protein Amino Acids in Lathyrus Sativus by  High-Performance Liquid Chromatography with Precolumn Derivatization with  6-Amino quinolyl-N-hydroxysuccinimidyl Carbamate (AQC). Chin. Chem. Lett. 2000,  11, 605.

29. Li, Z.; Huang, C.; Chen Q.; Wang, F.; ,Chen, Y. Studies on Chem  icalConstitution and Antitumor Activity of Galacto-glucan from Asparagus  cochinchinensis J. Lanzhou Uni. 2000, 36, 77-81

30. Zhao, L.; Chen, X.; Hu, Z.; Li, Q.F.; Chen, Q.; Li, Z. X. Analysis of  b-N-oxalyl-L-a,b-diaminopropionic acid and homoarginine in Lathyrus sativus by  capillary zone electrophoresis. Journal of Chromatogr, A 1999, 857, 295-302.