 基本信息哈工大基础与交叉科学研究院 哈尔滨工业大学科学园2A 1319室 哈尔滨市南岗区一匡街2号 3026信箱 电子邮件：chenqian@hit.edu.cn 教育经历 1993.9—1997.7 云南师范大学 化学系，本科，理学学士学位； 1997.9—2000.7 兰州大学化学系，有机化学硕士； 2002.10—2006.3 日本京都大学，药学博士学位； 2007.3—2008.4 日本理化学研究所，博士后 工作经历 2008.08--至今 哈尔滨工业大学 有机化学学科 副教授 l 金属有机化学：主要包括碳-碳键及碳-杂原子键的构筑、CO2，CO，O2等小分子的活化与利用、水的氧化与分解制氢等。 l 不对称合成：以设计、合成新型配体及催化剂为起点，探索新型催化反应为主要研究内容，以合成制备新型或有用的化合物为目标。主要包括：手性配体的设计、合成及其应用；天然产物的不对称全合成。 l 环境（水）中有机污染物的选择性氧化与降解：设计与合成具有新颖结构的配体，并深入研究其在铁、锰、钴催化的环境有机污染物的选择性氧化或深度氧化性降解的行为，探明理解催化氧化的机理。 l 重金属的选择性识别与去除：设计、合成具有优良配位螯合性能的分子，并深入研究其对Hg2+、Cd2+、Cu2+、Cr3+等重金属离子的选择性吸附行为，探明吸附与解离的机理，并将吸附性能优良的分子制备成可重复利用的吸附材料。 发表论文 1. Gao, G.L.; Chen, Q. Recent Advance in Utilities of Active Iodine Reagents as Organo-Catalyts in Organic Synthesis. Current Organocatalysis, 2015, 2, accepted. 2. Chen, Q.; Liu, C.; Guo, F.; Li, L. A Palladium-catalyzed Arylation of N-Acyl-N,O-Acetals with Arylboronic Reagents: Synthesis of Diarylmethylamines Protected by Easily Removable Acyl Group. Tetrahedron 2015, 71, 5337. 3. Chen, Q.; Li, L.; Guo, F.; Mao, Z The first application of C2-symmetric chiral sulfurous diamide as efficient sulfureolefin hybrid ligands for Rh-catalyzed asymmetric 1,4-addition reactions. Tetrahedron 2015, 71, http://dx.doi.org/10.1016/j.tet.2015.01.054. 4. Wang, Z.; Chen, Z.; Chang, J.; Shen, J.; Kang, J.; Yang, L.; Chen, Q. A novel cementitious microfiltration membrane: mechanisms of pore formation and properties for water permeation. RSC Adv., 2015, 5, 99–108 5. Chang, J.; Chen, Z.; Wang , Z.; Shen, J.; Chen, Q.; Kang, J.; Yang, L.; Liu, X.; Nie, X. Ozonation degradation of microcystin-LR in aqueous solution: Intermediates, byproducts and pathways. Water Research 2014, 63, 52-61. 6. Chen, Q.; Chen, C.; Guo F.; Xia, W. Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids with cyclic enones. Chem.Commun., 2013, 49, 6433. 7. Chen, Q. Recent Advances of Immobilized Catalysts for Enantioselective Processes. Current Organic Chemistry, 2013, 17, 1303-1324. 8. Han, Y.; Chen, Z.; Tong, L.; Yang, L.; Shen,J.; Wang, B; Liu, Y.; Chen, Q. Reduction of N-Nitrosodimethylamine with zero-valent zinc. Water Research 2013, 47, 216-224. 9. Chen, H.; Chen, Q. Synthesis of Chirl N,P-ligands Derived from L-Proline and Its Application to 1,3-Dipolar Cycloaddition. Chin. J. Org. Chem. 2013, 33, 848-853. 10. Hao, X.; Chen, Q.; Kuriyama, M.; Yamada, K.; Yamamoto, Y.; Tomioka, K. Rhodium-Catalyzed Asymmetric Phenylation of N-Phosphinoylarylimines with Triphenylborane. Catal. Sci. Tech., 2011, 1, 62-64. 11. Hao, X.; Chen, Q.; Yamada, K.; Yamamoto, Y.; Tomioka, K. Steric Influence of N-Phosphorus-arylimines on the Rhodium-Catalyzed Asymmetric Arylation. Tetrahedron 2011, 67, 6469-6473. 12. Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Wang, X.; Xu, J.; Xia, W.; Yang, C. pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(V) phosphate Cryst.Eng.Comm, 2010, 12, 595–603. 13. Yi, Z.; Yu,X.; Xia, W.; Zhao, L.; Yang, C.; Chen, Q.; Wang, X.; Xu, X.; Zhang, X. Influence of the steric hindrance of organic amines on the superamolecular network based on polyoxovanadates. Cryst.Eng.Comm., 2010, 12, 242–249. 14. Hao, X.; Kuriyama, M.; Chen, Q.; Yamamoto, Y.; Yamada, K.; Tomioka, K. Steric Tuning of the Amidomonophosphane-Rhodium(I) Catalyst in Asymmetric Addition of Arylboroxines to N-Phosphinoyl Aldimines. Org. Lett. 2009, 11, 4470-4473. 15. Zhao, G.; Yang, C.; Chen, Q.; Jin, J.; Zhang, X.; Zhao, L.; Xia, W. Photochemical studies on exo-bicyclo[2.1.1]hexyl and bicyclo[3.1.0]hexylaryl ketones: two approaches for synthesis of enantiomerically enrichedcyclopentene derivatives. Tetrahedron 2009, 65, 9952. 16. Chen, Q.; Kuriyama, M.; Hao, X.; Soeta, T.; Yamamoto, Y.; Yamada, K.; Tomioka, K. Chiral Amidophosphane-Rhodium(I)-Catalyzed Asymmetric Conjugate Arylation of Acyclic Enones with Arylboronic Acids. Chem. Pharm. Bull., 2009, 57, 1024-1027. 17. Yang, C.; Xia, W.-J.; Chen, Q.; Zhang, X.; Li, B.; Gou, B.-Q. Photochemical Studies on Benzonorbornene Derivatives: Medium Effects and Asymmetric Induction. Lett. Org. Chem. 2009, 6, 41-43. 18. Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Gu, X.; Xu, J.; Wang, X.; Yang, C.; Xu, X.; Xia, W. Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks. Dalton Trans., 2009, 9198–9206. 19. Chen, Q.; Soeta, T.; Kuriyama, M.; Yamada, K.; Tomioka, K. Efficient Catalytic Asymmetric Synthesis of trans-2-substituted 5-Arylcyclohexanones by Rhodium-Catalyzed Conjugate Arylation of Racemic 6-Substituted Cyclohexenones. Adv. Synth. Catal. 2006, 348, 2604-2608. 20. Chen, Q.; Kuriyama, M.; Soeta, T.; Hao, X.; Yamada, K.; Tomioka, K. Asymmetric Synthesis of 5-Arylcyclohexenones by Rhodium(I)-Catalyzed Conjugate Arylation of Racemic 5-(Trimethylsilyl)cyclohexenone with Arylboronic Acids. Org. Lett. 2005, 7, 4439-4441. 21. Kuriyama, M.; Soeta, T.; Hao, X.; Chen, Q.; Tomioka, K. N-Boc-L-Valine-Connected Amidomonophosphane-Rhodium(I) Catalyst for Asymmetric Arylation of N-Tosylarylimines with Arylboroxines. J. Am. Chem. Soc. 2004, 126, 8128-8129. 22. Lin, X.；Cai, Y. J.; Li, Z.; Chen, Q.; Liu, Z.L.; Wang, R. Structure determination, apoptosis induction, and telomerase inhibition of CFP-2, a novel lichenin from Cladonia furcata. Biochimica et Biophysica Acta 2003，1622, 99-108. 23. Chen, Q.; Chen, X.; Cai, Y.; Wang, F.; Li, Z. X. Isolation, Purification, and Analysis of Polysaccharides from Adenophora potaninii Kosrh. ZhongYaoCai, 2002, 25, 25-26. 24. Chen, Q.； Lin, X.； Cai, Y.； Li, Z.. Structural analysis of polysaccharide from Cladonia furcata and its activities. Chem. Res. Chin. Univ. 2001, 17, 226–227. 25. Chen, X.; Wang, F.; Chen, Q.; Qin, X. C.; Li, Z. X. Analysis of Neurotoxin 3-N-Oxalyl-l-2,3-diaminopropionic Acid and Its α-Isomer in Lathyrus sativus by High-Performance Liquid Chromatography with 6-Aminoquinolyl-N-hydroxysuccinimidyl Carbamate (AQC) Derivatization. J. Agric. Food Chem. 2000, 48, 3383-3386. 26. Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. Determination of neurotoxin 3-N-oxalyl-2,3-diaminopropionic acid and non-protein amino acids in Lathyrus sativus by precolumn derivatization with 1-fluoro-2,4-dinitrobenzene. J. Chromatogr. A, 2000, 883, 113-118. 27. Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. HPLC Determination of Neurotoxin β-N-oxalyl-L-α,β -diaminopropionic acid and Its α -Isomer in Lathyrus sativus by Precolumn Derivatization with 1-Fluoro-2,4-dinitrobenzene. Chin. Chem. Lett. 2000, 11, 435. 28. Wang, F.; Chen, X.; Chen, Q.; Qin, X.C.; Li, Z.X. Determination of Neurotoxin b-ODAP and Non-protein Amino Acids in Lathyrus Sativus by High-Performance Liquid Chromatography with Precolumn Derivatization with 6-Amino quinolyl-N-hydroxysuccinimidyl Carbamate (AQC). Chin. Chem. Lett. 2000, 11, 605. 29. Li, Z.; Huang, C.; Chen Q.; Wang, F.; ,Chen, Y. Studies on Chem icalConstitution and Antitumor Activity of Galacto-glucan from Asparagus cochinchinensis J. Lanzhou Uni. 2000, 36, 77-81 30. Zhao, L.; Chen, X.; Hu, Z.; Li, Q.F.; Chen, Q.; Li, Z. X. Analysis of b-N-oxalyl-L-a,b-diaminopropionic acid and homoarginine in Lathyrus sativus by capillary zone electrophoresis. Journal of Chromatogr, A 1999, 857, 295-302. |
